ISO 15202-2:2020

This document specifies a number of suitable methods for preparing test solutions from samples of airborne particulate matter collected using the method specified in ISO 15202-1, for subsequent determination of metals and metalloids by ICP-AES using the method specified in ISO 15202-3. It contains information about the applicability of the methods with respect to the measurement of metals and metalloids for which limit values have been set. The methods can also be used in the measurement of some metals and metalloids for which limit values have not been set but no information about its applicability is provided in this case.
NOTE    The sample preparation methods described in this document are generally suitable for use with analytical techniques other than ICP-AES, e.g. atomic absorption spectrometry (AAS) by ISO 8518[5] and ISO 11174[10] and inductively coupled plasma mass spectrometry (ICP-MS) by ISO 30011[11].
The method specified in Annex B is applicable when making measurements for comparison with limit values for soluble metal or metalloid compounds.
One or more of the sample dissolution methods specified in Annexes C through H are applicable when making measurements for comparison with limit values for total metals and metalloids and their compounds. Information on the applicability of individual methods is given in the scope of the annex in which the method is specified.
The following is a non-exclusive list of metals and metalloids for which limit values have been set (see References [14] and [15]) and for which one or more of the sample dissolution methods specified in this document are applicable. However, there is no information available on the effectiveness of any of the specified sample dissolution methods for those elements in italics.
Aluminium
Calcium
Magnesium
Selenium
Tungsten
Antimony
Chromium
Manganese
Silver
Uranium
Arsenic
Cobalt
Mercury
Sodium
Vanadium
Barium
Copper
Molybdenum
Strontium
Yttrium
Beryllium
Hafnium
Nickel
Tantalum
Zinc
Bismuth
Indium
Phosphorus
Tellurium
Zirconium
Boron
Iron
Platinum
Thallium
Caesium
Lead
Potassium
Tin
Cadmium
Lithium
Rhodium
Titanium
ISO 15202 is not applicable to the determination of elemental mercury or arsenic trioxide, since mercury vapour and arsenic trioxide vapour are not collected using the sampling method specified in ISO 15202-1.